Investigating Particle Size?Dependent Redox Kinetics and Charge Distribution in Disordered Rocksalt Cathodes
نویسندگان
چکیده
Understanding how various redox activities evolve and distribute in disordered rocksalt oxides (DRX) can advance insights into manipulating materials properties for achieving stable, high-energy batteries. Herein, the authors present reaction kinetics spatial distribution of are governed by particle size DRX materials. The size-dependent electrochemical performance is attributed to distinct cationic anionic at different sizes, which be tailored achieve optimal capacity stability. Overall, local charged domains particles display random heterogeneity caused isotropic delithiation pathways. Owing kinetic limitation, micron-sized exhibit a holistic “core-shell” charge distribution, whereas sub-micron show more uniform reactions throughout ensembles. Sub-micron increasing yet inferior cycling In summary, engineering effectively modulate
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ژورنال
عنوان ژورنال: Advanced Functional Materials
سال: 2022
ISSN: ['1616-301X', '1616-3028']
DOI: https://doi.org/10.1002/adfm.202110502